1st Chemical and Enterprise Identification
·Product identification
·Commonly known as polypropylene catalyst ActivCat ® 103d
·Application of Substances/Mixtures Polypropylene Catalysts
·Chemical Safety Technical Instructions Supplier Details
W. R. Grace Korea Limited
26, Jindallae-gil, Yeosu City, Jeollanam-do, 59614
KOREA
·For more information, please consult
Product supervision, Grace Europe Holdings Limited
MSDS.Davison@grace.com
·Emergency contact phone number:+(86) 532 8388 9090 (24 hours)
Overview of the second hazard
·Emergency situation overview:
Red, powder, will self ignite when exposed to air. Release flammable gases that can spontaneously ignite when exposed to water. Causing skin irritation. Causing severe eye irritation.
·Classification of substances or mixtures
flame
Spontaneous combustion solid type 1 H250 Exposure to air can cause spontaneous combustion
Class 1 substances that release flammable gases when exposed to water H260 Releasing flammable gases that can spontaneously ignite when exposed to water
Skin corrosion/irritation type 2 H315 Causing skin irritation
Severe eye injury/eye irritation Category 2 H319 Causing severe eye irritation
·Marking elements
·GHS labeling elements: This product is classified and labeled according to the Global Harmonized System for Classification and Labeling of Chemical Substances (GHS)· Hazard pictogram
GHS02 GHS07
·Warning: Danger
·Hazard Statement
H250 will self ignite when exposed to air
H260 releases flammable gases that can spontaneously ignite when exposed to water
H315 causes skin irritation
(Continued on page 2) RC
52.1.9
Printing date: June 17th, 2021
Chemical Safety Technical Manual
According to GB/T 16483-2008, GB/T 17519-2013 version number: 1.4
Page 2/14
Reviewed on June 17, 2021
Commonly known as polypropylene catalyst ActivCat ® 103d
(Continued on page 1)
H319 causes severe eye irritation
·Warning instructions
·Preventive measures
P210 Stay away from heat sources/sparks/open flames/hot surfaces. No smoking
P222 Do not come into contact with air
P223 Do not come into contact with water
P231+P232 Operate in inert gas. Moisture proof.
·Accident response
P305+P351+P338 If in eyes: Rinse with water carefully for a few minutes. If wearing contact lenses and easily removing them, remove the contact lenses.
P370+P378 · Safe Storage
P401
·Abandoned disposal
P501
Continue rinsing
In case of fire: Use dry sand to extinguish the fire.
Storage according to local/regional/national/international regulations
Dispose of contents/containers in accordance with local/regional/national/international regulations
3rd component/composition information
·Chemical characterization: mixture
·Describe storage in inert gas.
·Ingredients:
7631-86-9
Synthetic amorphous silica
amorphous silicon dioxide, chemically prepared
40-50%
·Dangerous ingredients:
Activated methylaluminoxane
Methyl aluminoxane
40-50%
Flammable solid Class 1, H228; Spontaneous combustion solid type 1, H250; Substances that release flammable gases when exposed to water
Category 1, H260
108-88-3
Phenylmethane
toluene
<3%
Flammable liquids Class 2, H225; Reproductive toxicity category 2, H361; Specific target organ systemic toxicity（
Repeated contact) Type 2, H373; Inhalation hazard Class 1, H304; Skin corrosion/irritation type 2,
H315; Specific target organ systemic toxicity (single exposure) Class 3, H336
107-83-5
Isohexane
2-methylpentane
<3%
Flammable liquids Class 2, H225; Inhalation hazard Class 1, H304; Harms to the water environment (chronic) Category 2, H411; Skin corrosion/irritation type 2, H315; Specific target organ systemic toxicity (single
Category 3 (secondary contact), H336
75-24-1
Trimethylaluminum
trimethylaluminium
<3%
Self igniting liquid type 1, H250; Class 1 substances that release flammable gases when exposed to water, H260; Skin decay
Erosion/irritation Class 1A, H314
Dimethyl zirconium ferrocene
Dimethyl zirconocene
<3%
Spontaneous combustion solid type 1, H250; Self heating substance type 2, H252; Substances that release flammable gases when exposed to water
Category 1, H260
287-92-3
Cyclopentane
cyclopentane
<3%
·Impurities and stabilizers:
108-88-3
Phenylmethane
toluene
Flammable liquids Class 2, H225; Reproductive toxicity category 2, H361; Specific target organ systemic toxicity (repeated exposure) Class 2, H373; Inhalation hazard Class 1, H304; Skin corrosion/irritation type 2, H315; Specific target device
Official system toxicity (single exposure) Category 3, H336
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