1st Chemical and Enterprise Identification
·Product identification
·Common name for polyethylene catalyst ActivCat ® 101b
·Application catalysts for substances/mixtures
·Chemical Safety Technical Instructions Supplier Details
W. R. Grace Korea Limited
26, Jindallae-gil, Yeosu City, Jeollanam-do, 59614
KOREA
·For more information, please consult
Product supervision, Grace Europe Holdings Limited
MSDS.Davison@grace.com
·Emergency contact phone number:+(86) 532 8388 9090 (24 hours)
Overview of the second hazard
·Emergency situation overview:
Yellow, powder, will self ignite when exposed to air. Release flammable gases that can spontaneously ignite when exposed to water. Causing severe skin burns and eye damage.
·Classification of substances or mixtures
flame
Spontaneous combustion solid type 1 H250 Exposure to air can cause spontaneous combustion
Class 1 substances that release flammable gases when exposed to water H260 Releasing flammable gases that can spontaneously ignite when exposed to water
corrosion
Skin corrosion/irritation Class 1A H314 Causing serious skin burns and eye damage
Severe eye injury/eye irritation Category 1 H318 Causing serious eye damage
·Marking elements
·GHS labeling elements: This product is classified and labeled according to the Global Harmonized System for Classification and Labeling of Chemical Substances (GHS)· Hazard pictogram
GHS02 GHS05
·Warning: Danger
·Identify hazardous ingredients on the label:
[Halides of alkyl terminated (poly) alkylaluminoxane and silicon dioxide reaction products] and bis (alkyl cyclopentadienyl) transition metal dihalides
Chemical reaction products
·Hazard Statement
Exposure to air can cause spontaneous combustion
(Continued on page 2) RC
48.1.28
Printing date: July 5th, 2019
Chemical Safety Technical Manual
According to GB/T 16483-2008, GB/T 17519-2013 version 1.1
Page 2/13
Reviewed on July 5th, 2019
Common name for polyethylene catalyst ActivCat ® 101b
(Continued on page 1)
Releasing flammable gases that can spontaneously ignite when exposed to water
Causing serious skin burns and eye damage
·Warning instructions
·Preventive measures
Do not come into contact with water
·Accident response
If skin (or hair) is contaminated: immediately remove all contaminated clothing. Wash skin with water/shower
If in the eyes: Rinse with water carefully for a few minutes. If wearing contact lenses and easily removing them, remove the contact lenses. Continue rinsing
Immediately call the emergency center/doctor
Specific treatment (see on this label)
·Safe storage
Storage must be locked
Store in inert gas.
·Abandoned disposal
Dispose of contents/containers in accordance with local/regional/national/international regulations
3rd component/composition information
·Chemical characterization: mixture
·Description of mixture: composed of the following components
·Dangerous ingredients:
Reaction products of alkyl terminated (poly) alkylaluminoxane and silicon dioxide halides with bis (alkyl cyclopentadienyl) transition metal dihalides
>95%
Spontaneous combustion solid type 1, H250; Self reactive substances type 2, H252; Class 1 substances that release flammable gases when exposed to water, H260; Skin corrosion/irritation Class 1A, H314; Severe eye injury/eye irritation
Category 1, H318
107-83-5
Isohexane
<2%
Flammable liquids Class 2, H225; Inhalation hazard Class 1, H304; Harm to water environment (chronic)
Category 2, H411; Skin corrosion/irritation type 2, H315; Specific target organ systemic toxicity (single dose)
Touch the third category, H336
108-88-3
Phenylmethane
<2%
Flammable liquids Class 2, H225; Reproductive toxicity category 2, H361; Specific target organ systemic toxicity (repeated exposure) Class 2, H373; Inhalation hazard Class 1, H304; Skin corrosion/irritation type 2,
H315; Specific target organ systemic toxicity (single exposure) Class 3, H336
287-92-3
Cyclopentane
<2%
Flammable liquids Class 2, H225; Harm to water environment (chronic) Category 3, H412
·Impurities and stabilizers:
108-88-3
Phenylmethane
Flammable liquids Class 2, H225; Reproductive toxicity category 2, H361; Specific target organ systemic toxicity (repeated exposure) Class 2, H373; Inhalation hazard Class 1, H304; Skin corrosion/irritation type 2, H315; Specific target device
Official system toxicity (single exposure) Category 3, H336
107-83-5
Isohexane
Flammable liquids Class 2, H225; Inhalation hazard Class 1, H304; Harms to the water environment (chronic) Category 2, H411; Skin corrosion/irritation type 2, H315; Specific target organ systemic toxicity (single exposure)
Category 3, H336
Methylaluminoxane
Flammable solid Class 1, H228; Spontaneous combustion solid type 1, H250; Class 1 substances that release flammable gases when exposed to water,
H260
287-92-3
Cyclopentane
Flammable liquids Class 2, H225; Harm to water environment (chronic) Category 3, H412
·For detailed information on risk terms listed in other information, please refer to Chapter 16.
RC