Chemical and enterprise identification
Product Information
Trade name: MMAO-3A 7 WT% AL IN METHYLCYCLOHEXANE
Use of substance/mixture: Main use: Component polymerization catalyst
Manufacturer or Supplier Name: Nouryon Functional Chemicals LLC
100 Matsonford Road, Building 5, Suite 550
US 19087 Radnor
United States
Phone number:+18008287929
Fax:+13125447188
Email address: polymer.amer@nouryon.com
Emergency consultation hotline: 24 hours:+31 57 06 79211, CHEMTREC-USA:1-800-424-9300,
CANUTEC-CANADA:1-613-996-6666, Emergency consultation hotline for chemical accidents: National Chemical Accident Emergency Response Center+86 532 8388 9090
Hazard Overview
Overview of Emergency Situations
Appearance and Appearance
shape
liquid
colour
colourless
smell
Characteristic
GB 6944/12268
United Nations number
UN 3399
United Nations Transport Name
Liquid organic metal substances, react with water, flammable
(Modified methylaluminoxane, methylcyclohexane)
category
four point three
subsidiary risk
three
Packaging category
I
Hazard Overview
MMAO-3A 7 WT% AL IN METHYLCYCLOHEXANE
Version 2 Revision Date: 17.07.2020 Print Date: 26.05.2022 CN / ZH
General advice
Immediate medical attention is required.
Leave the hazardous area.
Present this safety technical manual to the on-site doctor.
Physical and chemical hazards
Highly flammable liquids and vapors.
Release flammable gases that can spontaneously ignite when exposed to water.
Health hazards
inhalation
Inhalation of aerosols may cause irritation to the mucosa.
Thermal decomposition can lead to the release of irritating gases and vapors.
Contains organic solvents.
Swallowing and entering the respiratory tract can be fatal.
Inhalation may affect the central nervous system.
skin
Symptoms may appear delayed.
Causing severe skin burns.
Eyes
Causing serious eye damage.
Ingestion
Causing burns.
Swallowing may be harmful.
Swallowing and entering the respiratory tract can be fatal.
Environmental hazards
Environmental hazards cannot be ruled out during non professional operations and handling.
Toxic to aquatic organisms and has long-term sustained effects.
GHS hazard category
Flammable liquid, category 2
Substances and mixtures that release flammable gases when exposed to water, category 1
Acute toxicity, category 5, oral
Skin corrosion/irritation, category 1B
Severe eye injury/eye irritation, category 1
Specific target organ systemic toxicity (single exposure), category 3, anesthetic effects
Inhalation hazard, category 1
Acute (short-term) aquatic hazards, category 2
Long term aquatic hazards, category 2
GHS label elements
Pictogram
Signal words
Hazard Statement
Prevention instructions
:
danger
: H225 highly flammable liquid and vapor.
H260 releases flammable gases that can spontaneously ignite when exposed to water.
H303 Swallowing may be harmful.
H304 Swallowing and entering the respiratory tract may be fatal.
H314 causes severe skin burns and eye damage.
H336 may cause drowsiness or dizziness.
H411 is toxic to aquatic organisms and has long-term sustained effects.
Preventive measures:
P210 Keep away from heat sources/sparks/open flames/hot surfaces. Smoking is prohibited. P223 must not come into contact with water.
MMAO-3A 7 WT% AL IN METHYLCYCLOHEXANE
Version 2 Revision Date: 17.07.2020 Print Date: 26.05.2022 CN / ZH
Physical and chemical hazards
Highly flammable liquids and vapors.
Release flammable gases that can spontaneously ignite when exposed to water.
Health hazards
inhalation
P231+P232 operate in inert gas. Moisture proof.
P233 Keep the container closed.
P240 Container and loading equipment grounding/equipotential connection.
P241 Use explosion-proof equipment
P242 can only use tools that do not generate sparks.
P243 Take measures to prevent electrostatic discharge.
P261 Prevent inhalation of smoke, vapor, or spray.
Thoroughly clean the skin after homework P264.
P271 can only be used outdoors or in well ventilated areas.
P273 Avoid release into the environment.
P280 Wear protective gloves/protective clothing/protective goggles/protective masks.
Accident response:
P301+P310 If swallowed by mistake: Immediately call the emergency center/doctor.
P301+P330+P331 If swallowed by mistake: Rinse mouth. Do not induce vomiting.
P303+P361+P353 If skin (or hair) is contaminated: immediately remove all contaminated clothing. Wash skin/shower with water.
P304+P340+P310 If accidentally inhaled: Transfer person to fresh air and maintain a comfortable breathing position. Immediately call the emergency center/doctor.
P305+P351+P338+P310 If in eyes: Rinse with water carefully for a few minutes. If wearing contact lenses and easily removing them, remove the contact lenses. Continue rinsing. Immediately call the emergency center/doctor.
P312 If feeling unwell, call the emergency center/doctor.
P335+P334 Dust off small particles on the skin. Immerse in cold water/wrap with a damp bandage.
Clothes contaminated with P363 can only be reused after cleaning.
P370+P378000 fire: Please use dry sand, chemical dry powder, or vermiculite to extinguish the fire.
P391 Collect spillage.
Storage:
Store P402+P404 in a dry place. Store in a closed container.
Store P403+P233 in a well ventilated area. Keep the container sealed. Store P403+P235 in a well ventilated area. Maintain low temperature.
P405 storage area needs to be locked.
Disposal:
P501 Handle the substance/container according to local regulations.
Inhalation of aerosols may cause irritation to the mucosa.
Thermal decomposition can lead to the release of irritating gases and vapors.
Contains organic solvents.
Swallowing and entering the respiratory tract can be fatal.
Inhalation may affect the central nervous system.
Skin: Symptoms may appear delayed.
Causing severe skin burns.
MMAO-3A 7 WT% AL IN METHYLCYCLOHEXANE
Version 2 Revision Date: 17.07.2020 Print Date: 26.05.2022 CN / ZH
Eyes
Ingestion
Other information
Causing serious eye damage.
Causing burns.
Swallowing may be harmful.
Swallowing and entering the respiratory tract can be fatal.
Headache, dizziness, fatigue, nausea, and vomiting may be symptoms of excessive exposure.
Concentrations above the minimum limit value (TLV) can have a paralyzing effect.
Solvents can degrease the skin.
May cause drowsiness or dizziness.
test result
Acute oral toxicity
Acute toxicity estimate: 2942 mg/kg
Method: Calculation method
Environmental hazards
Environmental hazards cannot be ruled out during non professional operations and handling.
Toxic to aquatic organisms and has long-term sustained effects.
Other hazards
No further information available.